Most markdown processors support HTML content within a markdown document. Basically you could embed your markdown markup within a div which will centre its content. Following sample centers the image on the document.
<div style="text-align:center" markdown="1">
![Alt Text](/path/to/image "Caption")
</div>
You can also use CSS3 attribute selectors to select images with a certain path. Example
![Alt](image.jpg#right)
img[src*='#right']{ float: right; }